TECHICAL Series MATHEMATICS • INFORMATICS • PHYSICS Series PHILOLOGY Series ECONOMIC SCIENCES Sereies EDUCATIONAL SCIENCES Series LAW AND SOCIAL SCIENCES Series
Phosphomolybdic Heteropolyacid ? Catalyst of Allyl
(Azerbaijan State Oil Academy, 20 Azadlig ave, Baku, AZ1010, Azerbaijan Republic e-mail: asoa.rector@yahoo.com)
Vol LX • No. 4/2008
Siyavush Garayev, Gulahmad Talybov
Azerbaijan State Oil Academy, 20 Azadlig ave, Baku, AZ1010, Azerbaijan Republic
e-mail: asoa.rector@yahoo.com

 Keywords   

 Abstract
Alkoxyiodination of 1-vinyl-4-organilbenzols by the allyl alcohol and crystalline iodine in the presence of (NaK)4CaAl6Si30O72 clinoptylolite results in receiving of allyl β-iodethers with high yields. The last ones in the presence of heteropolyacid convert into substituted of 1,4-dioxane.

 Rezumat
Alcoxi iodurarea 1-vinil-4-organilbenzolilor cu alcooli alilici şi iod cristalin în prezenţa de clinoptilolit (NaK)4CaAl6Ci30O72 conduce la obţinerea de alil-β-iodoeteri cu randamente ridicate. Ultimii termeni amintiţi, în prezenţa de heteropoliacizi conduc la 1,4-dioxan substituit.



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